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Covering the essential aspects of the corrosion behavior
of metals in aqueous environments, this book is designed with the flexibility
needed for use in courses for upper-level undergraduate and graduate students,
for concentrated courses in industry, for individual study, and as a reference
book.
Contents:
Chapter 1 provides an overview of aqueous corrosion, emphasizing
corrosion as an interface phenomenon dependent on the variables defining
the metal, the environment, and the physical aspects of the interface
itself.
Chapter 2 gives the electrochemical background on electrode reactions
together with the principles governing the stability of metal/environment
systems, and includes a detailed discussion of Pourbaix diagrams and their
practical use.
Chapter 3 provides the electrochemical background on electrode
kinetics, and includes a discussion of models for anodic and cathodic
reactions at the metal/environment interface and for diffusion of species
to and from the interface, as well as introducing electrochemical measurements
to determine values of the kinetic parameters.
Chapter 4 emphasizes how the coupling of cathodic and anodic reactions
establish a mixed electrode or surface of corrosion cells, and how the
corrosion rate is established. Polarization curves are used to show how
these variables determine the corrosion current density and corrosion
potential.
Chapter 5 introduces the corrosion behavior of active-passive
type metals, emphasizing the more complex anodic polarization behavior
of these metals and the associated problems in interpreting their corrosion
behavior.
Chapter 6 describes the principles and procedures of electrochemical
measurements used to investigate corrosion behavior.
Chapter 7 discusses localized corrosion phenomena and covers specific
corrosion processes extending from pitting and crevice corrosion to stress-corrosion
cracking and corrosion fatigue. Examples of localized corrosion are provided.
Here the reader learns that corrosion involves a breadth of disciplines
extending from electrochemistry and materials science to solid and fluid
mechanics.
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