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37559 Reprint of the original 1961 text. Provides the necessary general background in relation to basic theory, conventions, and applications of reference electrodes. Devotes attention to experimental aspects of reference electrodes beyond the undergraduate student level. Includes critical and reasonably exhaustive accounts, with full bibliographies, of the experimental methods by which most reliable reference electrodes may be set up. Topics are examined from both a mechanistic and thermodynamic viewpoint. Deals with the hydrogen electrode and includes a comprehensive account of its mechanism of operation, as well as full details of all the useful forms of it that have been devised and used in practice. Discusses electrodes reversible to halide ions; pH-sensitive electrodes; glass electrodes; quin-hydrone electrodes and its congeners; metal-metal oxide electrodes; sulfide-reversible electrodes; nonaqueous electrode systems; membrane electrodes; electrodes in fused salt systems; and more. |
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